🔷 Variation of Atomic Radius in a Period (Left to Right):
✅ Trend:
Atomic radius decreases across a period.
🧠Why?
-
As we move from left to right, electrons are added to the same shell.
-
But at the same time, the nuclear charge (number of protons) increases.
-
This increased attraction pulls the electron cloud closer to the nucleus, reducing the atomic size.
📌 Example:
-
Na (Z=11) has a larger radius than Cl (Z=17), though both are in Period 3.
🔷 Variation of Atomic Radius in a Group (Top to Bottom):
✅ Trend:
Atomic radius increases down a group.
🧠Why?
-
As we move down a group, each element has one more electron shell than the one above.
-
Though nuclear charge also increases, the effect of added shells (shielding effect) is greater.
-
So, the outermost electrons are farther from the nucleus, making the atom larger.
📌 Example:
-
Li (Z=3) has a smaller radius than Cs (Z=55), though both are in Group 1.
✅ Conclusion:
| Direction | Trend in Atomic Radius | Reason |
|---|---|---|
| Across a period | Decreases | Increased nuclear charge pulls electrons inward |
| Down a group | Increases | Added shells increase distance from nucleus |
(9)